doiSerbia

Synthesis and characterization of tris[butyl-(1-methyl-3phenyl-propyl)-dithiocarbamato]cobalt(III) seskvitoluen

Kaluđerović Goran N. (Faculty of Chemistry, Belgrade)
Đinović Vesna M. (Faculty of Chemistry, Belgrade)
Trifunović Srećko R. (Faculty of Science - Department of Chemistry, Kragujevac)
Hodžić Ismet M. (Faculty of Chemistry, Belgrade)
Sabo Tibor J. (Faculty of Chemistry, Belgrade)

Anew bidentate ligand butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamate (bmΦpdtc) was prepared, as the sodium salt. In the reaction of hexaaminecobalt(III) chloride with NabmΦpdtc, the corresponding tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]cobalt(III) [Co(bmΦpdtc)3]complex was prepared. The complex was characterized by elemental analysis, infrared, electronic absorption, 1H and 13C-NMR spectroscopy.

Keywords: cobal(III) complex, dithiocarbamate, bidentate ligand.